Energetics of Organometallic Species

Energetics of Organometallic Species

4.11 - 1251 ratings - Source



An overview of modern organometallic thermochemistry, made by some of the most active scientists in the area, is offered in this book. The contents correspond to the seventeen lectures delivered at the NATO ASI Energetics of Organometallic Species (Curia, Portugal, September 1991), plus three other invited contributions from participants of that summer school. These papers reflect a variety of research interests, and discuss results obtained with several techniques. It is therefore considered appropriate to add a few preliminary words, attempting to bring some unity out of that diversity. In the first three chapters, results obtained by classical calorimetric methods are described. Modern organometallic thermochemistry started in Manchester, with Henry Skinner, and his pioneering work is briefly surveyed in the first chapter. The historical perspective is followed by a discussion of a very actual issue: the trends of stepwise bond dissociation enthalpies. Geoff Pilcher, another Manchester thermochemist, makes, in chapter 2, a comprehensive and authoritative survey of problems found in the most classical of thermochemical techniques - combustion calorimetr- applied to organometallic compounds. Finally, results from another classical technique, reaction-solution calorimetry, are reviewed in the third chapter, by Tobin Marks and coworkers. More than anybody else, Tobin Marks has used thermochemical values to define synthetic strategies for organometallic compounds, thus indicating an application of thermochemical data of which too little use has been made so far.Since they are not restricted to studying saturated organometallic complexes, ion beam techniques can be used to ... ions activate C-C and C-H bonds in alkanes by characterizing the energetics of the postulated intermediates in such reactions . 2. ... have been discussed in detail before [2-6], and involve the use of a aquot;guided aquot; ion beam tandem mass spectrometer [2, 7]. ... The sensitivity of the detector (a secondary electron scintillation ion detector [11]) is sufficiently high that all ions areanbsp;...


Title:Energetics of Organometallic Species
Author: José A. Martinho Simões
Publisher:Springer Science & Business Media - 2012-12-06
ISBN-13:

You must register with us as either a Registered User before you can Download this Book. You'll be greeted by a simple sign-up page.

Once you have finished the sign-up process, you will be redirected to your download Book page.

How it works:
  • 1. Register a free 1 month Trial Account.
  • 2. Download as many books as you like (Personal use)
  • 3. Cancel the membership at any time if not satisfied.


Click button below to register and download Ebook
Privacy Policy | Contact | DMCA